Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray solid which bears a close physical resemblance to the other five elements in the second column (group 2, or alkaline earth metals) of the periodic table: all group 2 elements have the same electron configuration in the outer electron shell and a similar crystal structure.
Magnesium is produced in large, aging stars from the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the interstellar medium where it may recycle into new star systems. Magnesium is the eighth most abundant element in the Earth’s crust and the fourth most common element in the Earth (after iron, oxygen and silicon), making up 13% of the planet’s mass and a large fraction of the planet’s mantle. It is the third most abundant element dissolved in seawater, after sodium and chlorine.
|Phase at STP||solid|
|Melting point||923 K (650 °C, 1202 °F)|
|Boiling point||1363 K (1091 °C, 1994 °F)|
|Density (near r.t.)||1.738 g/cm3|
|when liquid (at m.p.)||1.584 g/cm3|
|Heat of fusion||8.48 kJ/mol|
|Heat of vaporization||128 kJ/mol|
|Molar heat capacity||24.869 J/(mol·K)|
Elemental magnesium is a gray-white lightweight metal, two-thirds the density of aluminium. Magnesium has the lowest melting (923 K (1,202 °F)) and the lowest boiling point 1,363 K (1,994 °F) of all the alkaline earth metals.
Pure polycrystalline magnesium is brittle and easily fractures along shear bands. It becomes much more ductile when alloyed with small amount of other metals, such as 1% aluminium. Ductility of polycrystalline magnesium can also be significantly improved by reducing its grain size to ca. 1 micron or less.
General chemistry Magnesium 250g
It tarnishes slightly when exposed to air, although, unlike the heavier alkaline earth metals, an oxygen-free environment is unnecessary for storage because magnesium is protected by a thin layer of oxide that is fairly impermeable and difficult to remove.
Magnesium reacts with water at room temperature, though it reacts much more slowly than calcium, a similar group 2 metal. When submerged in water, hydrogen bubbles form slowly on the surface of the metal – though, if powdered, it reacts much more rapidly. The reaction occurs faster with higher temperatures (see safety precautions). Magnesium’s reversible reaction with water can be harnessed to store energy and run a magnesium-based engine. Magnesium also reacts exothermically with most acids such as hydrochloric acid (HCl), producing the metal chloride and hydrogen gas, similar to the HCl reaction with aluminium, zinc, and many other metals.
Magnesium is highly flammable, especially when powdered or shaved into thin strips, though it is difficult to ignite in mass or bulk. Flame temperatures of magnesium and magnesium alloys can reach 3,100 °C (5,610 °F), although flame height above the burning metal is usually less than 300 mm (12 in). Once ignited, such fires are difficult to extinguish, because combustion continues in nitrogen (forming magnesium nitride), carbon dioxide (forming magnesium oxide and carbon), and water (forming magnesium oxide and hydrogen, which also combusts due to heat in the presence of additional oxygen). This property was used in incendiary weapons during the firebombing of cities in World War II, where the only practical civil defense was to smother a burning flare under dry sand to exclude atmosphere from the combustion.
Magnesium may also be used as an igniter for thermite, a mixture of aluminium and iron oxide powder that ignites only at a very high temperature.
Organomagnesium compounds are widespread in organic chemistry. They are commonly found as Grignard reagents. Magnesium can react with haloalkanes to give Grignard reagents. Examples of Grignard reagents are phenylmagnesium bromide and ethylmagnesium bromide. The Grignard reagents function as a common nucleophile, attacking the electrophilic group such as the carbon atom that is present within the polar bond of a carbonyl group.
A prominent organomagnesium reagent beyond Grignard reagents is magnesium anthracene with magnesium forming a 1,4-bridge over the central ring. It is used as a source of highly active magnesium. The related butadiene-magnesium adduct serves as a source for the butadiene dianion.
Source of light Magnesium 250g
When burning in air, magnesium produces a brilliant-white light that includes strong ultraviolet wavelengths. Magnesium powder (flash powder) was used for subject illumination in the early days of photography. Later, magnesium filament was used in electrically ignited single-use photography flashbulbs. Magnesium powder is used in fireworks and marine flares where a brilliant white light is required. It was also used for various theatrical effects, such as lightning, pistol flashes, and supernatural appearances.